Interested participants can register at the cluin site for the internet seminar to be held on june, 2014 from 1. New version of nas natural attenuation software available. The citizens guide series is a set of 22 fact sheets that summarizes cleanup methods used at superfund and other sites. This guidance was developed to assist with remediation and cleanup actions at petroleum releases overseen by the petroleum tank cleanup section. Applicability of monitored natural attenuation at radioactively contaminated sites iaea technical reports series no. Demonstrationoftheuseofmonitorednaturalattenuation. Pdf calculation and use of firstorder rate constants for.
A riskbased approach using lines of evidence is widely used as a framework for monitored natural attenuation mna guidance. Monitored natural attenuation must not be assumed as appropriate for a site and is not simply a default remedy if other remedies are found unacceptable 52. Environmental protection agency office of research and development national risk management research laboratory ada, oklahoma 74820 project officer john t. The effects of contaminant concentration on the potential. Natural attenuation strategy for groundwater cleanup. Epa, defines monitored natural attenuation mna as the reliance on natural attenuation processes within the context of a carefully controlled and monitored site cleanup approach to achieve sitespecific remediation objectives within a time frame that is reasonable compared to that offered by other more active methods. General guidancelisted below are various guidance documents to help you better understand different aspects of the waste cleanup program.
This paper describes the development and application of a modeling system called natural attenuation software nas. The natural attenuation of organic compounds, particularly fuels and chlorinated solvents, has been subject to study for some time. Use of monitored natural attenuation at superfund, rcra corrective action, and underground storage tank sites sept. Use of monitored natural attenuation for groundwater remediation. Decision flowchart for the use of monitored natural attenuation mna and. The united states environmental protection agency u. The natural attenuation software tool was codeveloped by the u. Modflowmt3dms, and the natural attenuation software nas. The monitoring plan for natural attenuation must include sufficient groundwater monitoring wells, both in number and location, to measure groundwater flow directions, horizontal and vertical gradients and velocities, trends in contaminant concentrations within the. A citizens guide to monitored natural attenuation the citizens guide series is a set of 22 fact sheets that summarizes cleanup methods used at superfund and other sites. Monitored natural attenuation of chlorinated solvents. Six years ago, mna was recognised as a wellestablished remediation approach. United states environmental protection agency office of research and development washington, dc 20460 national risk management research laboratory ada, ok 74820 epa600f98022 may 1999 sefft monitored natural attenuation of chlorinated solvents u.
Since that time, there have been many advances in characterization, data interpretation and regulatory thinking that have become standard practice in our approach to monitored natural attenuation. The tool focuses on petroleum releases from underground storage tanks. Natural attenuation processes occur in most soil and groundwater systems and act, to varying degrees, on all contaminants. The term monitored natural attenuation mna refers to the reliance on natural attenuation processes within the context of a carefully controlled and monitored site cleanup approach to achieve sitespecific remediation objectives within a time frame that is reasonable compared to that offered by other more. Monitored natural attenuation mnaisaremediationtechniqueinwhichacontaminatedsiteis. Monitored natural attenuation mna is ongoing groundwater monitoring and associated field and laboratory work to confirm whether natural attenuation processes are acting at a sufficient rate to protect environmental values and to demonstrate that remedial objectives will be achieved within one generation, or about 30 years. A detailed evaluation of monitored natural attenuation effectiveness. This natural attenuation is recognized by the epa as a viable method of remediation for soil and groundwater.
Understanding site characterization to support the use of monitored natural attenuation mna for remediating inorganic contaminants in ground water is a major priority of research and technology transfer for the u. Monitored natural attenuation remedial action work plan. Monitorednaturalattenuationmnaisaremediationtechniqueinwhichacontaminatedsiteis. Methodology for estimating times of remediation associated. Monitored natural attenuation risk management research.
Feb 02, 2017 7 if the natural attenuation monitoring plan meets the criteria of subsection 62780. A decision framework for applying monitored natural. Site screening and technical guidance for monitored natural attenuation at doe. Monitored natural attenuation guidance updated for the. Monitored natural attenuation may be applied as a riskbased re mediation strategy if it can be established that.
No part of this document may be reproduced, stored in a retrieval system, or. The term mna refers to the reliance on natural attenuation processes to achieve the applicable ground water remediation standard. These processes take place whether or not other active cleanup measures are in. The mission of the department of ecology is to protect, preserve, and enhance washington s environment. No part of this document may be produced, stored in a retrieval system, or transmitted, in any form.
Monitored natural attenuation mna is an important, common groundwater remediation technology used for treating some dissolved groundwater contaminants. Use of monitored natural attenuation for groundwater. Defines natural attenuation, explains how mna can be applied under trrp for groundwater, establishes administrative and technical processes to apply mna, illustrates the technical demonstrations to be made to the tceq. If, during the long term monitoring program, mna is determined to no longer represent a protective remedy, the investigator must. Pdf applicability of monitored natural attenuation at. Evaluation of monitored natural attenuation at petroleum. Demonstrationoftheuseofmonitorednaturalattenuationasa remediationtechnologydemomna projectscopeandobjectives. Edwin is currently president and chief technical officer cto at comnipex corporation leading innovative projects in geoenvironmental area focusing on modern technologies and materials for soil and groundwater remediation including nanotechnology as well as waste management. Epa remedial technology fact sheet scope of this fact sheet. Monitored natural attenuation mna as a sound remedial alternative at contaminated sites. Demonstrationoftheuseofmonitorednaturalattenuationas. This step provides further criteria to confirm whether monitored natural attenuation is likely to be effective.
Calculation and use of firstorder rate constants for monitored natural attenuation studies article pdf available january 2002 with 666 reads how we measure reads. Fact sheet monitored natural attenuation of chlorinated. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. The report refers to and makes use of previously published literature and guidelines, which are considered as key docu. The software can plot input data and simulation results to aid in decision making. Natural attenuation refers to the reduction, weakening, and eventual elimination of toxic substances in the soil and groundwater by natures own processes.
This guidance covers the application of natural attenuation for remediating petroleum contaminated groundwater, including. Pdf the prospect of more efficient, economically advantageous management strategies has driven the development of contaminated land. Technology ground water, surface water, and leachate 3. Its now been 15 years since the publication of natural attenuation of fuels and chlorinated solvents in the subsurface by todd wiedemeier, hanadi rifai, chuck newell and john wilson. Introduction natural subsurface processessuch as dilution, volatilization, biodegradation, adsorption, and chemical reactions with subsurface materialsare allowed to reduce contaminant concentrations to acceptable levels. This document provides technical guidance on how to evaluate the feasibility and performance of cleanup action alternatives that use natural attenuation, either alone or in conjuction with other cleanup action components. This report discusses in detail the necessary prerequisites, processes involved and applicability of nonintervention as a strategy for dealing with radioactive contamination. Use of monitored natural attenuation as a remediation strategy involves filing a formal regulatory application to allow natural biological, chemical, and physical processes to treat groundwater contaminants, and conducting ongoing monitoring to verify that these processes are effective. The usepa will be hosting an internet seminar on this updated information on monitored natural attenuation via their contaminated site cleanup information cluin website.
Nas was designed as a screening tool to estimate times of remediation tors, associated with monitored natural attenuation mna, to lower groundwater contaminant concentrations to regulatory limits. Use of monitored natural attenuation at superfund, rcra. Scientists monitor these conditions to make sure natural attenuation is working. Mna relies on natural attenuation processes to achieve sitespecific remediation objectives within a reasonable time frame compared to more active approaches. This means that natural attenuation is certainly not a donothing option. Thornton prox im ity to potent ial rec ept ors and compl exit y of hydro geol ogic al. Rcra corrective action, and underground storage tank sites is a revision of a. The basic physical processes which, unaided by deliberate human intervention, reduce the concentration, toxicity, or mobility of such contaminants, are fairly well understood. Nas natural attenuation software is a software package that provides a decisionmaking framework for determining the time needed to clean up groundwater contamination sites. The basic physical processes which, unaided by deliberate human intervention, reduce the concentration, toxicity, or mobility of. Methodology for estimating times of remediation associated with monitored natural attenuation prepared in cooperation with the southern division, naval facilities engineering command and the naval facilities engineering service center u. Epa remedial technology fact sheet epa 600f98022, 1998 this fact sheet explains what monitored natural attenuation means when the term is used to describe a potential strategy to remediate a contaminated site.
Pdf application of monitored natural attenuation in contaminated. Particular emphasis is placed on modelling tools as an integral element of monitored natural attenuation mna. Rbca risk assessment software 9usepa as quoted in consim. Designing monitoring programs to effectively evaluate the. Natural attenuation software free download windows version. Monitored natural attenuation option for plume management 6 2 natural attenuation concepts 2. Nas natural attenuation software has a userfriendly graphical interface that helps environmental professionals estimate how long it will take for natural attenuation processes to clean up contaminant plumes. Mna may be a stand alone option or a part of a strategy involving other activities, for instance source treatment. As implied by the title of this policy document, monitoring will be required to evaluate the longterm effectiveness of natural attenuation and to assure protection of human health and the environment. Water stored in the pores and crevices of the material below the land surface, including soil, rock and fill material. How to evaluate alternative cleanup technologies for. Waste cleanup program guidance florida department of. Challenges in monitoring the natural attenuation of spatially variable plumes. Natural attenuation must be clearly demonstrated on a.
It generally describes a range of physical and biological processes, which, unaided by deliberate human intervention, reduce the concentration, toxicity, or mobility of chemical or radioactive contaminants. Environmental site assessment and remediation winnipeg. This guidance document does not explain how natural attenuation occurs. A decision flowchart for the use of monitored natural. The package has been upgraded with the release of version 2. This fact sheet explains what monitored natural attenuation means. Nas consists of a combination of computational tools implemented in three main. Monitored natural attenuation is a strategy and a set of procedures used to demonstrate that physiochemical andor biological processes in an aquifer will reduce concentrations of undesirable substances to levels below regulatory concern.
Monitored natural attenuation risk management research us epa. Monitored natural attenuation remedial action work plan for. New paradigms, technologies, and applications from rice university. It is intended that this report will form the foundation for the agencys technical appraisal of monitored natural attenuation schemes on a sitespecific basis. Monitored natural attenuation remedial action work plan for test area north final groundwater remediation, operable unit 107b 1. Epa600r04179 january 2005 monitored natural attenuation of mtbe as a risk management option at leaking underground storage tank sites john t. Under suitable conditions, monitored natural attenuation mna can be a costeffective strategy. A decision framework for applying monitored natural attenuation processes to metals and radionuclides in groundwater. Methodology for estimating times of remediation associated with monitored natural attenuation by francis h. This is a software package developed by sandia national laboratories to.
A long term monitoring ltm plan is necessary to evaluate the effectiveness of the mna ground water remedy. However, when appropriately evaluated and monitored, we can safely allow nature to do the. Natural attenuation software nas is a screening tool to estimate remediation timeframes for monitored natural attenuation mna to lower groundwater contaminant concentrations to regulatory limits, and to assist in decisionmaking on the level of source zone treatment in conjunction with mna using sitespecific remediation objectives. Monitored natural attenuation guidance updated for the 21st. Monitored natural attenuation of mtbe as a risk management. A decision to rely on natural attenuation processes as part of a site. Natural attenuation of petroleum hydrocarbons and chlorinated. This guideline for the use of monitored natural attenuation for groundwater remediation has been prepared by the department of environmental protection dep to provide information to consultants, local government authorities, industry and other interested parties in the use of this groundwater remediation option in western australia wa. Pdf challenges in monitoring the natural attenuation of. Introduction this remedial action work plan has been prepared in accordance with the federal facility agreement and consent order for the idaho national engineering laboratory doeid 1991 by the.
Monitored natural attenuation mna is ongoing groundwater monitoring and associated field and laboratory work to confirm whether natural attenuation processes are acting at a sufficient rate to protect environmental values, and to demonstrate that remedial objectives will be achieved within either a specified time period or a site. Monitored natural attenuation rijkswaterstaat environment. Geological survey waterresources investigations report 034057. Guidance on the assessment and monitoring of natural.
A decision flowchart for the use of monitored natural attenuation and enhanced attenuation at sites with chlorinated organic plumes figure 1. Monitored natural attenuation of inorganic contaminants in. Learn natural attenuation of groundwater contaminants. Natural attenuation relies on natural processes to decrease or attenuate concentrations of contaminants in soil and groundwater. Guidance on natural attenuation for petroleum releases. Guidance for establishing temporary point of compliance beyond the source property june 2017 word, 48 kbguidance for requests for additional site assessment rasas and remedial action plan addenda rapas october 26, 2011 pdf, 3. Geological survey waterresources investigations report 03 4057. The objective of the monitoring program shall be to meet the applicable no further action criteria of rule 62780. Environmental protection agencys office of research and development and the national risk management. Evaluation of monitored natural attenuation at petroleum release sites. Modeling efforts resulted in a successful negotiation with the epa for monitored natural attenuation as the accepted remediation alternative. Monitored natural attenuation mna is an important, common groundwater.